In a chemical reaction, reactants are not always mixed according to stoichiometric ratio. Often one reactant is used in large excess to ensure expensive reactant is completely used.
🧪 STEPS TO FIND LIMITING REACTANT
1. Calculate moles of each reactant from given amounts.
2. Calculate moles of product (e.g., CO₂) that would form from each reactant, using reaction stoichiometry.
3. The reactant that yields the least amount of product is the limiting reactant – it controls product amount.
⚗️ Example 15.16 (glucose + oxygen)
C₆H₁₂O₆ (s) + 6O₂ (g) → 6CO₂ (g) + 6H₂O (l)
Given: 25 g glucose (molar mass 180) & 40 g oxygen (32).
✔ Glucose gives 0.834 mol CO₂ (less than 1.25 from O₂). ➡ limiting reactant = glucose
Amount CO₂ produced = 0.834 × 44 = 36.7 g (approx).
🧠Memorization tip: “Limiting = Least product moles”. Compare product moles from each reactant; smallest is the boss. Use BCA table: Before, Change, After.
🔁 Quick Check 15.8 (from text)
If you react 100 g of chlorine gas with 500 g of KI, which reactant will be the limiting reactant?
✅ Solution: Molar mass Cl₂ = 71 g/mol → moles Cl₂ = 100/71 = 1.41 mol.
Molar mass KI = 166 g/mol → moles KI = 500/166 = 3.01 mol.
Reaction: 1 mol Cl₂ requires 2 mol KI. For 1.41 mol Cl₂ need 2.82 mol KI (available 3.01, so KI excess). Limiting reactant = Cl₂
⭐ Tip: always compare required vs available.
📝 10 MCQs quiz · limiting reactant
Instructions: click on answer. Correct turns ✔green, wrong turns ✘ red. Use submit to see score & key.
Score: — / 10
🔑 Answer key will appear after submit.
📅 Lesson Planner & Activity
Track your study & apply with a challenge problem.
✅ Today’s stoichiometry goals
⚡ Activity: Find limiting reactant
2 Na (s) + Cl₂ (g) → 2 NaCl (s) Given: 46 g sodium (Na = 23) and 71 g chlorine (Cl₂ = 71).
Which reactant limits? How many g NaCl formed?
🧪 Solution:
Moles Na = 46/23 = 2.0 mol ; Moles Cl₂ = 71/71 = 1.0 mol.
2 mol Na requires 1 mol Cl₂ (from 2:1 ratio). Both present in exact ratio → either can be limiting? Actually stoichiometric ratio means both are completely consumed, but by definition both limit (no excess). Often we say “both limit”. Limiting reactant: Both / either (stoichiometric)
Mass NaCl = 2 mol NaCl × 58.5 = 117 g.
⭐ After planner, review your quiz errors. Use notebook for calculations.
📚 Good guidelines for students
• Always write balanced equation first.
• Convert masses to moles — that’s your starting line.