⚡ Writing ionic formulas · using charges
📘 Rule: electrically neutral compound
Potassium permanganate: permanganate ion MnO4– + potassium K+ → KMnO4
Ammonium carbonate: NH4+ and CO32- → two ammonium ions needed: (NH4)2CO3
Aluminium sulphate (example 16.5): Al3+ + SO42- → cross charges: Al2(SO4)3
📋 Table 16.1 – Common Polyatomic ions
| Ion | Name | Ion | Name | Ion | Name |
|---|---|---|---|---|---|
| CH3COO– | acetate | Cr2O72- | dichromate | NO2– | nitrite |
| NH4+ | ammonium | HCO3– | bicarbonate | C2O42- | oxalate |
| CO32- | carbonate | HSO4– | bisulfate | ClO4– | perchlorate |
| ClO4– | chlorate | HSO3– | bisulfite | MnO4– | permanganate |
| ClO3– | chlorite | OH– | hydroxide | PO43- | phosphate |
| CrO42- | chromate | ClO– | hypochlorite | SO42- | sulfate |
| CN– | cyanide | NO3– | nitrate | SO32- | sulfite |
🧠 Quick memorization & tips
• “Nick the Camel” for -ate vs -ite: chlorate (ClO3–) has more oxygen than chlorite (ClO2–).
• Permanganate MnO4– : deep purple, charge -1 (like permanganate “minus one”).
• Ammonium NH4+ is the only common cation polyatomic; think “ammonia + H”.
• Sulfate SO42- vs sulfite SO32-: “ate” has 4 oxygen, “ite” has 3.
• To write formula: swap charges (crisscross) and reduce if needed. Ex: Ca2+ + PO43- → Ca3(PO4)2.
⏳ 35‑min lesson planner
📝 16.2 Quick Check!
1. Write formulas using oxidation numbers: Aluminum nitride, Sodium sulfate, Sodium hydrogen carbonate.
AlN, Na2SO4, NaHCO3
2. Write using charges on ions: Ammonium acetate, Calcium phosphate, Potassium chromate.
NH4CH3COO, Ca3(PO4)2, K2CrO4
🔬 10 MCQs · ionic formulas
Select one answer per question. Correct turns green, wrong ones red after submit.
📌 good guidelines
• Write cation first, then anion. Use parentheses for multiple polyatomic ions.
• Total positive charge must balance total negative charge.
• Memorize common ions from table 16.1: acetate, nitrate, sulfate, carbonate, phosphate.
• Practise criss‑cross method: Mg2+ + PO43- → Mg3(PO4)2.
• Always check if subscripts can be reduced (but with polyatomics, keep inside bracket).