MDCAT Chemistry 2008, Solved Paper with Detailed Answers

4o

In an electrochemical series, standard electrode potentials are arranged on the basis of:

  • A) pH scale
  • B) pOH scale
  • C) Hydrogen scale
  • D) pKa scale
  • Answer: C) Hydrogen scale

The reaction responsible for electricity production in a Voltaic cell is:

  • A) Hydrolysis reaction
  • B) Oxidation reaction
  • C) Redox reaction
  • D) Reduction reaction
  • Answer: C) Redox reaction
  1. Glucose is converted into ethanol by the enzyme in yeast:
  • A) Urease
  • B) Invertase
  • C) Sucrase
  • D) Zymase
  • Answer: D) Zymase
  1. The rate of reaction involving ions can be studied by the _ method:
  • A) Dilatometric
  • B) Refractometric
  • C) Optical rotation
  • D) Electrical conductivity
  • Answer: D) Electrical conductivity
  1. When one mole of gaseous hydrogen ions are dissolved in water to form an infinitely dilute solution, the amount of heat liberated is:
  • A) -1891 kJ/mol
  • B) -1075 kJ/mol
  • C) -499 kJ/mol
  • D) -1562 kJ/mol
  • Answer: C) -499 kJ/mol
  1. Energy required to remove an electron from the outermost shell of an isolated gaseous atom in the ground state is called:
  • A) Electron affinity
  • B) Lattice energy
  • C) Ionization energy
  • D) Crystal energy
  • Answer: C) Ionization energy
  1. Which of the following alkali metal carbonates decomposes on heating to form an oxide and liberate CO₂?
  • A) Li₂CO₃
  • B) Mg₂CO₃
  • C) K₂CO₃
  • D) Na₂CO₃
  • Answer: A) Li₂CO₃
  1. Calcium is essential for plants and stimulates the development of:
  • A) Leaves
  • B) Fruits
  • C) Root hairs
  • D) Branches
  • Answer: C) Root hairs
  1. Which sulfate is not soluble in water?
  • A) Sodium sulfate
  • B) Barium sulfate
  • C) Potassium sulfate
  • D) Zinc sulfate
  • Answer: B) Barium sulfate
  1. In Group III-A of the Periodic Table, the trend in element densities is:
    • A) A gradual increase
    • B) A gradual decrease
    • C) First decreases, then increases
    • D) First increases, then decreases
    • Answer: A) A gradual increase
  2. White lead has one of the following properties:
    • A) Acidic
    • B) Crystalline
    • C) Amorphous
    • D) Neutral
    • Answer: B) Crystalline
  3. The strongest acid among the following is:
    • A) HF
    • B) HI
    • C) HCl
    • D) HBr
    • Answer: B) HI
  4. The noble gas used in cancer radiotherapy is:
    • A) Radon
    • B) Xenon
    • C) Krypton
    • D) Argon
    • Answer: A) Radon
  5. In NH₄Cl, which type of bonding is present?
    • A) Ionic
    • B) Covalent
    • C) Coordinate covalent
    • D) All of these
    • Answer: D) All of these
  6. In the electrolysis of CuSO₄ solution using copper electrodes, the substance deposited at the cathode is:
    • A) Copper metal
    • B) Copper ions
    • C) Hydrogen
    • D) Oxygen
    • Answer: A) Copper metal
  7. Aldehydes can be synthesized by the oxidation of:
    • A) Primary alcohols
    • B) Secondary alcohols
    • C) Organic acids
    • D) Inorganic acids
    • Answer: A) Primary alcohols
  8. The products of sugar fermentation are ethanol and:
    • A) Water
    • B) Oxygen
    • C) Carbon dioxide
    • D) Sulfur dioxide
    • Answer: C) Carbon dioxide
  9. Which element forms long chains with oxygen?
    • A) Carbon
    • B) Silicon
    • C) Nitrogen
    • D) All of these
    • Answer: B) Silicon
  10. The correct order of density for Group III-A elements is:
    • A) Li < Na < K
    • B) Al < Ga < In
    • C) B < Ga < In
    • D) In < Al < Ga
    • Answer: C) B < Ga < In
  11. Hydrogen burns in chlorine to produce hydrogen chloride. The ratio of masses in this reaction is:
    • A) 1:35.5
    • B) 2:35.5
    • C) 1:71
    • D) 2:70
    • Answer: A) 1:35.5

  1. The gas law which combines Charles’s and Boyle’s laws is:
    • A) Avogadro’s Law
    • B) Combined Gas Law
    • C) Dalton’s Law
    • D) Graham’s Law
    • Answer: B) Combined Gas Law
  2. When sodium metal reacts with water, it produces hydrogen gas and:
    • A) Sodium chloride
    • B) Sodium hydroxide
    • C) Sodium sulfate
    • D) Sodium oxide
    • Answer: B) Sodium hydroxide
  3. One mole of water vapor occupies a volume of 22.4 L at:
    • A) Standard temperature and pressure (STP)
    • B) Room temperature
    • C) Zero degrees Celsius
    • D) High pressure
    • Answer: A) Standard temperature and pressure (STP)
  4. In titration, phenolphthalein is used as an indicator in:
    • A) Strong acid-strong base titration
    • B) Weak acid-strong base titration
    • C) Strong acid-weak base titration
    • D) Neutralization reactions
    • Answer: B) Weak acid-strong base titration
  5. The ideal gas equation is expressed as:
    • A) PV = nRT
    • B) P + V = nRT
    • C) PRT = V/n
    • D) PV/n = RT
    • Answer: A) PV = nRT
  6. The element with the highest ionization energy in the periodic table is:
    • A) Helium
    • B) Hydrogen
    • C) Oxygen
    • D) Fluorine
    • Answer: A) Helium
  7. The primary structural component in proteins is:
    • A) Polypeptides
    • B) Lipids
    • C) Sugars
    • D) Nucleotides
    • Answer: A) Polypeptides
  8. Which one of the following is an essential fatty acid?
    • A) Stearic acid
    • B) Oleic acid
    • C) Linoleic acid
    • D) Acetic acid
    • Answer: C) Linoleic acid
  9. Baking soda is chemically known as:
    • A) Sodium carbonate
    • B) Sodium bicarbonate
    • C) Sodium hydroxide
    • D) Sodium sulfate
    • Answer: B) Sodium bicarbonate
  10. Sucrose on hydrolysis gives:
    • A) Glucose + Maltose
    • B) Glucose + Fructose
    • C) Fructose + Galactose
    • D) Maltose + Lactose
    • Answer: B) Glucose + Fructose
  11. In chemical kinetics, the order of a reaction is determined by:
    • A) Concentration of products
    • B) Concentration of reactants
    • C) Rate-determining step
    • D) Overall reaction equation
    • Answer: B) Concentration of reactants
  12. The element that exhibits catenation property predominantly is:
    • A) Nitrogen
    • B) Phosphorus
    • C) Sulfur
    • D) Carbon
    • Answer: D) Carbon
  13. The process used to separate petroleum into various components is called:
    • A) Filtration
    • B) Crystallization
    • C) Fractional distillation
    • D) Electrolysis
    • Answer: C) Fractional distillation
  14. A basic oxide will typically react with water to form a:
    • A) Neutral solution
    • B) Acidic solution
    • C) Basic solution
    • D) Salt only
    • Answer: C) Basic solution
  15. The oxidation number of chromium in potassium dichromate (K₂Cr₂O₇) is:
    • A) +3
    • B) +5
    • C) +6
    • D) +7
    • Answer: C) +6
  16. The color of Fe²⁺ ions in aqueous solution is:
    • A) Blue
    • B) Green
    • C) Yellow
    • D) Brown
    • Answer: B) Green
  17. The compound used as an anesthetic in minor surgeries is:
    • A) Ethanol
    • B) Ether
    • C) Acetone
    • D) Benzene
    • Answer: B) Ether
  18. Chlorofluorocarbons (CFCs) are harmful because they:
    • A) Pollute water
    • B) Deplete the ozone layer
    • C) Cause acid rain
    • D) Reduce soil fertility
    • Answer: B) Deplete the ozone layer
  19. The functional group in aldehydes is:
    • A) -COOH
    • B) -CHO
    • C) -OH
    • D) -COO
    • Answer: B) -CHO
  20. A solution that resists changes in pH when small amounts of acid or base are added is called:
    • A) Buffer
    • B) Acidic
    • C) Basic
    • D) Neutral
    • Answer: A) Buffer

  1. The number of moles of solute present in 1 liter of a solution is called:
    • A) Molarity
    • B) Molality
    • C) Normality
    • D) Formality
    • Answer: A) Molarity
  2. A compound that contains both ionic and covalent bonds is:
    • A) HCl
    • B) NH₃
    • C) NaCl
    • D) NaOH
    • Answer: D) NaOH
  3. The main component of natural gas is:
    • A) Methane
    • B) Ethane
    • C) Propane
    • D) Butane
    • Answer: A) Methane
  4. Which one of the following is an alloy of copper and zinc?
    • A) Brass
    • B) Bronze
    • C) Steel
    • D) Solder
    • Answer: A) Brass
  5. When a base dissolves in water, it releases:
    • A) OH⁻ ions
    • B) H⁺ ions
    • C) O₂ molecules
    • D) CO₂ molecules
    • Answer: A) OH⁻ ions
  6. The pH of a neutral solution at 25°C is:
    • A) 7
    • B) 0
    • C) 1
    • D) 14
    • Answer: A) 7
  7. The ion responsible for the hardness of water is:
    • A) Na⁺
    • B) K⁺
    • C) Mg²⁺
    • D) H⁺
    • Answer: C) Mg²⁺
  8. Which organic compound is a common solvent and known as wood alcohol?
    • A) Ethanol
    • B) Methanol
    • C) Propanol
    • D) Butanol
    • Answer: B) Methanol
  9. A triglyceride is formed by the reaction of glycerol with:
    • A) Carboxylic acids
    • B) Fatty acids
    • C) Amino acids
    • D) Hydrocarbons
    • Answer: B) Fatty acids
  10. Electrolysis of molten NaCl yields:
    • A) Na and Cl₂
    • B) NaClO
    • C) H₂ and Cl₂
    • D) NaOH and Cl₂
    • Answer: A) Na and Cl₂
  11. Which one of the following is used to detect proteins?
    • A) Benedict’s test
    • B) Biuret test
    • C) Tollen’s test
    • D) Iodine test
    • Answer: B) Biuret test
  12. Among the following, the most reactive metal is:
    • A) Iron
    • B) Copper
    • C) Potassium
    • D) Magnesium
    • Answer: C) Potassium
  13. The monomer of polythene is:
    • A) Ethene
    • B) Propene
    • C) Styrene
    • D) Vinyl chloride
    • Answer: A) Ethene
  14. The bleaching action of chlorine is due to:
    • A) Oxidation
    • B) Reduction
    • C) Hydrolysis
    • D) Precipitation
    • Answer: A) Oxidation
  15. Aluminum is extracted from its ore by:
    • A) Reduction
    • B) Electrolysis
    • C) Distillation
    • D) Crystallization
    • Answer: B) Electrolysis
  16. Which of the following is a synthetic polymer?
    • A) Wool
    • B) Nylon
    • C) Silk
    • D) Cotton
    • Answer: B) Nylon
  17. The process of rusting involves:
    • A) Oxidation
    • B) Reduction
    • C) Sublimation
    • D) Distillation
    • Answer: A) Oxidation
  18. The ideal gas equation holds true for:
    • A) All conditions
    • B) High pressure and low temperature
    • C) Low pressure and high temperature
    • D) All solids
    • Answer: C) Low pressure and high temperature
  19. The color of potassium permanganate in solution is:
    • A) Pink
    • B) Yellow
    • C) Green
    • D) Blue
    • Answer: A) Pink
  20. The compound that releases OH⁻ ions in water is called a:
    • A) Base
    • B) Acid
    • C) Salt
    • D) Nonelectrolyte
    • Answer: A) Base